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- W2023697188 abstract "Abstract The cyclic voltammetric response of Hg(cyclam) 2+ at mercury electrodes consists of a single cathodic and a single anodic wave. By contrast, two anodic and two cathodic peaks appear in cyclic voltammograms for the free cyclam ligand (1,4,8,11-tetraazacyclotetradecane) in unbuffered solutions at mercury electrodes. An explanation for the differences in the voltammetric responses is provided. It is based on the acid—base chemistry of cyclam and the unequal diffusion coefficients of protonated cyclam and the hydroxide ion." @default.
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- W2023697188 title "Why the reduction of Hg(cyclam)2+ exhibits a single voltammetric peak while the oxidation of Hg in the presence of cyclam produces two voltammetric peaks" @default.
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- W2023697188 doi "https://doi.org/10.1016/0022-0728(92)80233-t" @default.
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