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- W2023697382 abstract "O,O-Dimethyl-S-(2,4-dinitrophenyl) thiophosphat (I) ist nicht lagerungsbeständig und zersetzt sich schon im Dunkeln und in Abwesenheit von Luftsauerstoff bei 0–20° allmählich, schneller beim Erhitzen in inerten Lösungsmitteln, zu Bis(2,4-dinitrophenyl) disulfid (II) und Trimethylphosphat. In Gegenwart von Luftsauerstoff reagiert I mit n-Butanol unter Bildung von II und n-Butyl-dimethylphosphat. Mit Cyclohexylamin bildet sich aus I in Gegenwart oder Abwesenheit von Luftsauerstoff II, sowie Bis(2,4-dinitrophenyl)-sulfid, 2,4-Dinitrophenyl-methylsulfid und das Cyclohexylammonium-salz der Cyclohexylamido-methylphosphorsäure. Die Umsetzung von 2,4-Dinitrophenylrhodanid mit Triäthylphosphit in Dimethylsulfoxyd (DMSO) liefert neben Dimethylsulfid und Triäthylphosphat Bis(2,4-dinitrophenyl)-sulfid und O,O,O-Triäthylthiophosphat. O,O-Dimethyl-S-(2,4-dinitrophenyl) phsophorothioate (I) cannot be stored indefinitely and decomposes readily even in the dark and absence of air-oxygen at 0–20°, faster on heating in inert solvents, to give bis(2,4-dinitrophenyl) disulfide (II) and trimethylphosphate. In the presence of air-oxygen I reacts with n-butanol with formation of II and n-butyl dimethylphosphate. With cyclohexylamine and I, in the presence or absence of air-oxygen, formation of II as well as bis(2,4-dinitrophenyl) sulfide, 2,4-dinitrophenyl-methylsulfide and the cyclohexylammonium salt of cyclohexylamido-methylphosphoric acid takes place. 2,4-Dinitrophenyl-thiocyanate reacts with triethylphosphite in dimethylsulfoxide (DMSO) to give dimethylsulfide and triethylphosphate as well as bis(2,4-dinitropheny)-sulfide and O,O,O-triethylphosphorothioate." @default.
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- W2023697382 date "1967-01-01" @default.
- W2023697382 modified "2023-09-25" @default.
- W2023697382 title "O,O-dimethyl-S-(2,4-dinitrophenyl)thiophosphat" @default.
- W2023697382 cites W1974323360 @default.
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- W2023697382 doi "https://doi.org/10.1016/s0040-4020(01)83355-x" @default.
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