FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023697747> ?p ?o ?g. }

• W2023697747 abstract "The kinetics of base hydrolysis of (αβS) (salicylato) (tetraethylenepentamine) cobalt(III) have been investigated in aquo-organic solvent media at 15.0 < t, °C < 40.0, and I = 0.10 mol dm (ClO4−) using propane-2-ol (⩽70% v/v), t-butanol (⩽60% v/v), acetone (⩽70% v/v), acetonitrile (⩽50% v/v), and ethylene glycol (⩽70% v/v) as cosolvents. Both the spontaneous and base-catalyzed hydrolysis of the phenoxide species [(tetren)CoO2CC6H4O]+ were appreciably accelerated by the cosolvents PriOH, ButOH, Me2CO, and MeCN. On the contrary the base hydroylsis (k2) was retarded while spontaneous aquation (k1) was accelerated to a small extent with increased EG content. Variation of log k1 and log k (k = k2 at I = 0) with mole fraction (X0.S) or reciprocal of the relative permitivity (Ds−1) of the media were nonlinear. The transfer free energy of the transition state relative to that of the initial state of the substrate for transfer of species from water to mixed solvents also varied nonlinearly with X0.S, or Ds−1 indicating solvent specificity. The activation parameters, ΔH≠ and ΔS≠ varied nonlinearly with solvent composition exhibiting extrema. The preferential solvation and solvent structural effects mediated the kinetics and energetics of the reaction. © 1995 John Wiley & Sons, Inc." @default.
• W2023697747 created "2016-06-24" @default.
• W2023697747 creator A5037273053 @default.
• W2023697747 creator A5050548756 @default.
• W2023697747 creator A5090963837 @default.
• W2023697747 date "1995-10-01" @default.
• W2023697747 modified "2023-09-23" @default.
• W2023697747 title "Effects of solvents on the reactions of coordination complexes: Part 20. Kinetics and mechanism of base hydrolysis of (??S) (Salicylato) (Tetraethylenepentamine) Cobalt(III) in aquo-organic solvent media" @default.
• W2023697747 cites W1977245190 @default.
• W2023697747 cites W1978778698 @default.
• W2023697747 cites W1994252779 @default.
• W2023697747 cites W1994520625 @default.
• W2023697747 cites W2006961799 @default.
• W2023697747 cites W2011447313 @default.
• W2023697747 cites W2029511765 @default.
• W2023697747 cites W2032805074 @default.
• W2023697747 cites W2034778667 @default.
• W2023697747 cites W2035810795 @default.
• W2023697747 cites W2037357166 @default.
• W2023697747 cites W2050127072 @default.
• W2023697747 cites W2053207955 @default.
• W2023697747 cites W2073667017 @default.
• W2023697747 cites W2074858492 @default.
• W2023697747 cites W2081757424 @default.
• W2023697747 cites W2117216034 @default.
• W2023697747 cites W2126639997 @default.
• W2023697747 cites W2136583887 @default.
• W2023697747 cites W2147279041 @default.
• W2023697747 cites W2165405275 @default.
• W2023697747 cites W2001587174 @default.
• W2023697747 doi "https://doi.org/10.1002/kin.550271008" @default.
• W2023697747 hasPublicationYear "1995" @default.
• W2023697747 type Work @default.
• W2023697747 sameAs 2023697747 @default.
• W2023697747 citedByCount "4" @default.
• W2023697747 crossrefType "journal-article" @default.
• W2023697747 hasAuthorship W2023697747A5037273053 @default.
• W2023697747 hasAuthorship W2023697747A5050548756 @default.
• W2023697747 hasAuthorship W2023697747A5090963837 @default.
• W2023697747 hasConcept C121332964 @default.
• W2023697747 hasConcept C132439834 @default.
• W2023697747 hasConcept C134306372 @default.
• W2023697747 hasConcept C147789679 @default.
• W2023697747 hasConcept C148093993 @default.
• W2023697747 hasConcept C148898269 @default.
• W2023697747 hasConcept C155647269 @default.
• W2023697747 hasConcept C178790620 @default.
• W2023697747 hasConcept C179104552 @default.
• W2023697747 hasConcept C185592680 @default.
• W2023697747 hasConcept C2777516009 @default.
• W2023697747 hasConcept C2777713963 @default.
• W2023697747 hasConcept C2780161600 @default.
• W2023697747 hasConcept C2780471494 @default.
• W2023697747 hasConcept C2781213060 @default.
• W2023697747 hasConcept C33923547 @default.
• W2023697747 hasConcept C42058472 @default.
• W2023697747 hasConcept C515602321 @default.
• W2023697747 hasConcept C62520636 @default.
• W2023697747 hasConcept C94412978 @default.
• W2023697747 hasConcept C95121573 @default.
• W2023697747 hasConceptScore W2023697747C121332964 @default.
• W2023697747 hasConceptScore W2023697747C132439834 @default.
• W2023697747 hasConceptScore W2023697747C134306372 @default.
• W2023697747 hasConceptScore W2023697747C147789679 @default.
• W2023697747 hasConceptScore W2023697747C148093993 @default.
• W2023697747 hasConceptScore W2023697747C148898269 @default.
• W2023697747 hasConceptScore W2023697747C155647269 @default.
• W2023697747 hasConceptScore W2023697747C178790620 @default.
• W2023697747 hasConceptScore W2023697747C179104552 @default.
• W2023697747 hasConceptScore W2023697747C185592680 @default.
• W2023697747 hasConceptScore W2023697747C2777516009 @default.
• W2023697747 hasConceptScore W2023697747C2777713963 @default.
• W2023697747 hasConceptScore W2023697747C2780161600 @default.
• W2023697747 hasConceptScore W2023697747C2780471494 @default.
• W2023697747 hasConceptScore W2023697747C2781213060 @default.
• W2023697747 hasConceptScore W2023697747C33923547 @default.
• W2023697747 hasConceptScore W2023697747C42058472 @default.
• W2023697747 hasConceptScore W2023697747C515602321 @default.
• W2023697747 hasConceptScore W2023697747C62520636 @default.
• W2023697747 hasConceptScore W2023697747C94412978 @default.
• W2023697747 hasConceptScore W2023697747C95121573 @default.
• W2023697747 hasLocation W20236977471 @default.
• W2023697747 hasOpenAccess W2023697747 @default.
• W2023697747 hasPrimaryLocation W20236977471 @default.
• W2023697747 hasRelatedWork W1966193957 @default.
• W2023697747 hasRelatedWork W1971853591 @default.
• W2023697747 hasRelatedWork W1986359844 @default.
• W2023697747 hasRelatedWork W1993533967 @default.
• W2023697747 hasRelatedWork W2005115757 @default.
• W2023697747 hasRelatedWork W2005697729 @default.
• W2023697747 hasRelatedWork W2022528628 @default.
• W2023697747 hasRelatedWork W2023508204 @default.
• W2023697747 hasRelatedWork W2025328264 @default.
• W2023697747 hasRelatedWork W2026633242 @default.
• W2023697747 hasRelatedWork W2034077069 @default.
• W2023697747 hasRelatedWork W2050998997 @default.
• W2023697747 hasRelatedWork W2051022351 @default.
• W2023697747 hasRelatedWork W2060324066 @default.
• W2023697747 hasRelatedWork W2110938848 @default.
• W2023697747 hasRelatedWork W2952109938 @default.

• next