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- W2023704690 abstract "Several hydrates of tin(IV) chloride, e.g., SnCl4·xH2O (x=2, 3, 4 and 5) and SnCl4·yD2O (y=3, 4 and 5), were investigated by means of the nuclear quadrupole resonance (NQR) due to 35Cl and the Mossbauer effect due to 119Sn. The NQR-frequencies were observed at the temperature of liquid nitrogen and room temperature; they were found to range from 17.656 to 21.439 MHz. The Mossbauer effect was investigated only at the temperature of liquid nitrogen; it resulted in isomer shifts ranging from 0.275 to 0.350 mm/sec. The NQR-frequency and the isomer shift decreased with an increase in the number of water molecules in the hydrates, and the relationship between the NQR-frequency and the isomer shift was nearly linear. This relation was interpreted in terms of the transfer of the s-electrons of the tin atom to the chlorine atoms. Furthermore, it was revealed that there was a significant difference between the Sn-Cl bond of the hydrates and that of ammonium chlorostannate." @default.
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- W2023704690 date "1969-09-01" @default.
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- W2023704690 title "The Bond Character of the Sn–Cl Bonds in the Hydrates of Tin (IV) Chloride" @default.
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- W2023704690 doi "https://doi.org/10.1246/bcsj.42.2509" @default.
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