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- W2023705637 abstract "Electron transfer reactions in ion pairs, exciplexes, innersphere and intramolecular reactions are carried out in sufficiently stable complexes including a donor and an acceptor. In the present work nonadiabatic electron transfer reactions in such complexes are considered. Vibrations along the donor—acceptor bond are shown to lead to statistical and dynamic effects. Due to the modulation of the electron tunneling matrix element and electronic energy by donor—acceptor vibrations the free energy of activation contains an entropic term and an additional reorganization energy, connected with the reorganization of the donor—acceptor bond, appears. The dynamic effect of donor—acceptor vibrations is displayed in the dependence of the nonadiabatic electron transfer probability on the medium friction (viscosity)." @default.
- W2023705637 created "2016-06-24" @default.
- W2023705637 creator A5003059556 @default.
- W2023705637 date "1992-07-01" @default.
- W2023705637 modified "2023-09-25" @default.
- W2023705637 title "Donor—acceptor vibrations in nonadiabatic electron transfer reactions" @default.
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- W2023705637 doi "https://doi.org/10.1016/0301-0104(92)87127-u" @default.
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