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- W2023706782 abstract "A new molecular system, 2,11-dithio[4,4]metametaquinocyclophane containing a quinone moiety, was designed and synthesized. As the quinone moiety can readily be converted into an aromatic π-system (hydroquinone) upon reduction, the nanomechanical molecular cyclophane system exhibits a large flapping motion like a molecular flipper from the electrochemical redox process. The conformational changes upon reduction and oxidation are caused by changes of nonbonding interaction forces (devoid of bond formation/breaking) from the edge-to-face to face-to-face aromatic interactions and vice versa, respectively." @default.
- W2023706782 created "2016-06-24" @default.
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- W2023706782 date "2002-10-01" @default.
- W2023706782 modified "2023-10-12" @default.
- W2023706782 title "An Electrochemically Controllable Nanomechanical Molecular System Utilizing Edge-to-Face and Face-to-Face Aromatic Interactions" @default.
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- W2023706782 doi "https://doi.org/10.1021/ol0268541" @default.
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