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- W2023711244 abstract "The ion energy distribution and the electroionization efficiency curves of H+ and D+ from methane and methane-d4 have been examined. The existence of thermal ions is unambiguously evidenced and the two lowest appearance thresholds of H+ are measured at (21.3 ± 0.3) eV and (22.17 ± 0.1) eV. At both energies the protons have to be formed through dissociative autoionization. The present results closely parallel those of the dissociative excitation experiments on methane. The Jortner—Rice model for dissociation of polyatomic molecules is invoked to account for both the appearance of H+ and high-Rydberg H atoms from CH4." @default.
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- W2023711244 date "1979-11-01" @default.
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- W2023711244 title "Dissociative autoionization as a mechanism for the proton formation from methane and methane-d4 by low energy electron impact" @default.
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- W2023711244 doi "https://doi.org/10.1016/0301-0104(79)85210-6" @default.
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