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• W2023714863 abstract "Abstract Powder samples of CrSbVO6 were synthesized from a mixture of appropriate oxides by the solid state reaction technique and investigated by the electron paramagnetic resonance (EPR) in the 4–300 K temperature range. At room temperature the EPR spectrum consisted of two widely differing components: a narrow (∼10 mT) line centered at gna = 1.967 and an intense, almost Lorentzian broad (∼100 mT) line at gbr = 1.975. The EPR spectral parameters (linewidth, g-factor, amplitude, integrated intensity) of both components displayed a marked thermal dependence. The temperature dependence of the broad component showed a very interesting behavior – its amplitude increased on cooling from room temperature, reaching a maximum at 50 K and decreased sharply on further cooling. The narrow line in the EPR spectrum of CrSbVO6 was attributed to strongly interacting V4+ and Cr3+ monomers and Cr3+–Cr3+ pairs, while the broad line was due to the V4+–V4+ dimers and spin clusters involving Cr3+ and V4+ ions." @default.
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• W2023714863 date "2008-10-01" @default.
• W2023714863 modified "2023-09-25" @default.
• W2023714863 title "Magnetic interactions in CrSbVO6 studied by EPR" @default.
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• W2023714863 doi "https://doi.org/10.1016/j.jnoncrysol.2008.06.095" @default.
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