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- W2023717136 abstract "Effects of high humidity on γ-aminopropyltriethoxysilane adsorbed from vapor on a plasma grown Al2O3 surface were studied by measuring inelastic electron tunneling spectra of the sample exposed to 75% relative humidity for various lengths of time. The majority of the initially adsorbed silane is desorbed by the exposure to high humidity and the remaining silane undergoes hydrolysis. Ethanol produced by hydrolysis is probably oxidized to acetaldehyde on the Al2O3 surface. Interaction between the vapor deposited silane and the surface OH groups is inferred from the frequency shifts of the stretching mode of the surface OH groups. Reorientation of the adsorbed silane molecules in the tunneling barrier caused by the initial exposure to high humidity is observed." @default.
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- W2023717136 date "1983-12-01" @default.
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- W2023717136 title "Inelastic electron tunneling spectroscopic study of the silane coupling agents II. γ-aminopropyltriethoxysilane adsorbed from vapor on aluminum oxide surface and effects of high humidity" @default.
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- W2023717136 doi "https://doi.org/10.1016/0021-9797(83)90037-1" @default.
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