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- W2023720705 abstract "Interconfigurational 4 f 10 5 d ↔ 4 f 11 transitions of the Er 3+ ion in the YAG host were studied under both VUV photon (synchrotron radiation) and electron beam excitation. It was found that the lowest low-spin 5 d level of the Er 3+ ion has a rather large energy gap to the next lower 4 f 2 D (2) 5/2 crystal-field level, which results in a relatively low rate of nonradiative transitions from this 5 d level leading to the appearance of weak spin-allowed 5 d –4 f luminescence at low temperature. The lowest high-spin 5 d level, from which spin-forbidden 5 d –4 f radiative transitions could occur potentially, is situated only at ∼500 cm −1 above the 4 D 1/2 level. Such close location allows fast depopulation of the 5 d level resulting in the absence of spin-forbidden 5 d –4 f luminescence and appearance of 4 D 1/2 4 f –4 f luminescence." @default.
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- W2023720705 date "2009-04-01" @default.
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- W2023720705 title "5d–4f luminescence of Er3+ in YAG:Er3+" @default.
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- W2023720705 doi "https://doi.org/10.1016/j.optmat.2008.11.017" @default.
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