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• W2023721179 abstract "A family of organic-inorganic hybrid frameworks, {[Ln(H(2)O)(4)(pdc)](4)} [XMo(12)O(40)].2H(2)O (Ln = La, Ce, and Nd; X = Si and Ge; H(2)pdc = pyridine-2,6-dicarboxylate), have been prepared under hydrothermal conditions and characterized by single crystal X-ray diffraction analyses, elemental analyses, IR, and thermal gravimetric analyses. Single crystal X-ray diffraction reveals that all six compounds are isostructural, and each consists of a zeolite-like four-connected three-dimensional cationic framework {[Ln(H(2)O)(4)(pdc)](4)}(4+) and ball-shaped Keggin type [XMo(12)O(40)](4-) as templates. Interesting channels exist in the cationic framework with the gismondine topology, and these channels intersect each other to form large cavities, which array in a zigzag fashion and are occupied by nanosized [XMo(12)O(40)](4-) counterions. Moreover, these compounds display strong photoluminescent properties in the solid state at room temperature." @default.
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• W2023721179 date "2009-03-02" @default.
• W2023721179 modified "2023-10-18" @default.
• W2023721179 title "Lanthanide−Organic Cation Frameworks with Zeolite Gismondine Topology and Large Cavities from Intersected Channels Templated by Polyoxometalate Counterions" @default.
• W2023721179 doi "https://doi.org/10.1021/ic801846h" @default.
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