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• W2023721943 abstract "The microwave spectra of normal and deuterated allyl mercaptan (CH2CHCH2SH and CH2CHCH2SD) were studied in the region from 8 to 33 gHz. About 160 lines have been assigned to the ground and the excited vibrational states of the “gauche” form of the molecule. The rotational constants of the ground vibrational state of the normal species are A = 20041.68 mHz, B = 2795.72 mHz, C = 2701.10 mHz and those of deuterated species are A = 18540.30 mHz, B = 2774.35 mHz, C = 2662.71 mHz. The Stark effect measurements gave the components of the molecular dipole moment of the normal molecule as μa = 1.24D, μb = 0.21D, μc = 0.42D, and total moment μt = 1.33D; and μa = 1.27D, μb = 0.19D, μc = 0.40D, and μt = 1.34D for the deuterated species. Kraitchman's equations were used to calculate the position of the thiol (-SH) hydrogen atom." @default.
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• W2023721943 date "1969-01-01" @default.
• W2023721943 modified "2023-10-10" @default.
• W2023721943 title "Microwave spectrum, dipole moment, and molecular structure of allyl mercaptan" @default.
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• W2023721943 doi "https://doi.org/10.1016/0022-2852(69)90338-5" @default.
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