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- W2023726082 abstract "The sub-structure of Bi2Sr2Ca1Cu2O8 can best be described on a non-centric orthorhombic A2aa cell, which permits the oxygen in the BiO plane to move off the center of the Bi square to approach to within 2.2 Å of a pair of Bi atoms. Each Bi then has two close oxygens within the BiO plane, and a third at 2.12 Å connecting to the CuO layer. The new structure permits the apparent Bi valence to approach 3+ with a more reasonable Bi-O co-ordination than for earlier approximate structural models. This model satisfies the high resolution neutron data of Bordet et al., while agreeing in part with the co-ordination proposed on chemical grounds by von Schnering et al." @default.
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- W2023726082 date "1988-08-01" @default.
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- W2023726082 title "A note on the symmetry and Bi valence of the superconductor Bi2Sr2Ca1Cu2O8" @default.
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- W2023726082 doi "https://doi.org/10.1016/0921-4534(88)90126-8" @default.
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