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- W2023729761 abstract "The measurement of the well known 2Πg transient N2−ion is reported as a function of its distance from a Pt substrate, for N2 deposited on the surface or embedded in the bulk of an Ar, Kr and Xe multilayers film. The excitation function for the v=1 vibration loss were recorded between 0 and 4 eV with an electron spectrometer having a resolution of 18 meV. By comparing the oscillatory structure observed in these experiments with the gas-phase structure, the energy shift and the broadening of the temporary anion state are deduced. In the distance to substrate experiment the resonance is shifted progressively from a value of −0.62 eV at 32 layers to a value of −1.34 eV at 1 layer. In the surface to bulk experiment the resonance is displaced from a surface value of −0.62, −0.72, and −0.89 eV to an averaged bulk value of −0.89, −1.15, and −1.35 eV for Ar, Kr, and Xe, respectively." @default.
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- W2023729761 date "1990-01-01" @default.
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- W2023729761 title "The 2Πg shape resonance of N2 near a metal surface and in rare gas solids" @default.
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- W2023729761 doi "https://doi.org/10.1016/0368-2048(90)80155-4" @default.
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