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- W2023733032 abstract "Thermally stable hydrido(phenyl)- amd hydrido(methyl)-platinum(II) complexes trans-[PtH(R)L2] (R = Ph, L = PMe3, PEt3, PPh3, P-i-Pr3, P-t-BuMe2, P-t-Bu2 Me; R = Me, L = PPh3, P-i-Pr3 ) are obtained in good yield by treatment of trans-[PtX(R)L2] (X = Cl, OH, NHCOMe) or trans-[PtR(MeOH)L2]+ with methanolic sodium methoxide or sodium borohydride; thermally unstable cis-hydrido(methyls) PtH(Me){Ph2P(CH2)nPPh2}(n = 2 or 3) are formed by elimination of CO2 from the corresponding formates Pt(O2CH)Me {Ph2P(CH2)nPPh2}." @default.
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- W2023733032 date "1980-10-01" @default.
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- W2023733032 title "Hydrido(phenyl)- and hydrido(methyl)-platinum(II) complexes via thermally unstable methoxo and formato complexes" @default.
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- W2023733032 doi "https://doi.org/10.1016/s0022-328x(00)84536-2" @default.
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