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- W2023742786 abstract "Photolysis of [NiII(μ-Cl)Cl(IPr)]2 (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) activates the Ni–Cl bonds to furnish [NiI(μ-Cl)(IPr)]2. Consistent with this photochemistry, a TD-DFT calculation for square planar Ni(II) centre reveals that light excitation leads to the population of orbitals with σ*(Ni–Cl) character." @default.
- W2023742786 created "2016-06-24" @default.
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- W2023742786 date "2013-01-01" @default.
- W2023742786 modified "2023-09-23" @default.
- W2023742786 title "Photoactivation of metal–halogen bonds in a Ni(ii) NHC complex" @default.
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- W2023742786 doi "https://doi.org/10.1039/c2dt32885b" @default.
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