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- W2023743687 abstract "Die spezifische Wärme von Eisen, Kobalt und Nickel wurde mit einem neuen, unter Schutzgas betriebenen, quasiadiabatisch arbeitenden Kalorimeter im Bereich von Raumtemperatur bis jeweils dicht unterhalb des Schmelzpunktes gemessen. Mit den Meßergebnissen für Eisen werden zunächst die thermodynamischen Funktionen der beiden Eisenmodifikationen im Bereich der γ-Phase neu bestimmt. Dann wird der Gesamtbetrag der spezifischen Wärme der drei Metalle näherungsweise in seine Anteile zerlegt. Es gelingt, den magnetischen Anteil zur spezifischen Wärme infolge der starken Anomalie am Curiepunkt quantitativ vom gemessenen Temperaturverlauf abzuspalten, so daß ein Vergleich mit dem theoretisch erwarteten Verlauf möglich ist. The specific heats of iron, cobalt, and nickel are measured in a quasi-adiabatic operating calorimeter in the range from room temperature to a temperature near the melting point of each metal. Using the results for iron the thermo-dynamic functions of the two modifications of iron in the range of the γ-phase are determined and the total amount of the specific heat of the three metals is then decomposed nearly in its parts. It succeeds to separate the magnetic part of the specific heat, in consequence of the strong anomaly at the Curie point, quantitatively from the measured temperature dependence so that a comparison with the theoretically expected dependence is possible." @default.
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- W2023743687 date "1965-01-01" @default.
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- W2023743687 title "Die spezifische Wärme von Eisen, Kobalt und Nickel im Bereich hoher Temperaturen" @default.
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- W2023743687 doi "https://doi.org/10.1002/pssb.19650120142" @default.
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