Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023756509> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2023756509 endingPage "2939" @default.
- W2023756509 startingPage "2934" @default.
- W2023756509 abstract "A new type of luminescent label has been synthesized and a range of carbohydrates has been derivatized with various fluorescent probes. Amine-containing labels were readily transformed with chloroacetylchloride into the corresponding fluorescent chloroacetamide reagents 1–4. Suitably blocked monosaccharides containing either a free thio 9, hydroxyl 11, or carboxyl 17 functionality have been conjugated with (a) 4-chloroacetamido labels 1 and 2, (b) with 4-aminobenzophenone 5, and (c) with 1-dimethyl-1-aminonaphthalene-5-sulfonylchloride 21, to form the fluorescent carbohydrate conjugates 10, 16, 18, and 20. Direct derivatization of the unblocked disaccharides 22 and 23 was achieved by reductive amination with amines 5 and 7 and sodium cyanoborohydride affording the 1-deoxyglycit-1-yl derivatives 24–26, which were characterized by 13 C nmr spectroscopy. The synthesis of fluorescent polysaccharides is exemplified by the condensation of 9-anthraldehyde with chitosan either via Schiff 's base formation to afford 32, or via reductive alkylation to form 33." @default.
- W2023756509 created "2016-06-24" @default.
- W2023756509 creator A5036463211 @default.
- W2023756509 creator A5062045415 @default.
- W2023756509 date "1981-10-15" @default.
- W2023756509 modified "2023-10-09" @default.
- W2023756509 title "Synthesis of fluorescent probe – carbohydrate conjugates" @default.
- W2023756509 doi "https://doi.org/10.1139/v81-425" @default.
- W2023756509 hasPublicationYear "1981" @default.
- W2023756509 type Work @default.
- W2023756509 sameAs 2023756509 @default.
- W2023756509 citedByCount "18" @default.
- W2023756509 countsByYear W20237565092014 @default.
- W2023756509 countsByYear W20237565092015 @default.
- W2023756509 countsByYear W20237565092017 @default.
- W2023756509 countsByYear W20237565092018 @default.
- W2023756509 countsByYear W20237565092019 @default.
- W2023756509 crossrefType "journal-article" @default.
- W2023756509 hasAuthorship W2023756509A5036463211 @default.
- W2023756509 hasAuthorship W2023756509A5062045415 @default.
- W2023756509 hasConcept C112613896 @default.
- W2023756509 hasConcept C118859902 @default.
- W2023756509 hasConcept C121332964 @default.
- W2023756509 hasConcept C131779359 @default.
- W2023756509 hasConcept C134306372 @default.
- W2023756509 hasConcept C158711907 @default.
- W2023756509 hasConcept C161790260 @default.
- W2023756509 hasConcept C164361826 @default.
- W2023756509 hasConcept C178790620 @default.
- W2023756509 hasConcept C179998833 @default.
- W2023756509 hasConcept C185592680 @default.
- W2023756509 hasConcept C197336794 @default.
- W2023756509 hasConcept C21951064 @default.
- W2023756509 hasConcept C2776923573 @default.
- W2023756509 hasConcept C2779321498 @default.
- W2023756509 hasConcept C2779938440 @default.
- W2023756509 hasConcept C33923547 @default.
- W2023756509 hasConcept C40875361 @default.
- W2023756509 hasConcept C521977710 @default.
- W2023756509 hasConcept C62520636 @default.
- W2023756509 hasConcept C91881484 @default.
- W2023756509 hasConceptScore W2023756509C112613896 @default.
- W2023756509 hasConceptScore W2023756509C118859902 @default.
- W2023756509 hasConceptScore W2023756509C121332964 @default.
- W2023756509 hasConceptScore W2023756509C131779359 @default.
- W2023756509 hasConceptScore W2023756509C134306372 @default.
- W2023756509 hasConceptScore W2023756509C158711907 @default.
- W2023756509 hasConceptScore W2023756509C161790260 @default.
- W2023756509 hasConceptScore W2023756509C164361826 @default.
- W2023756509 hasConceptScore W2023756509C178790620 @default.
- W2023756509 hasConceptScore W2023756509C179998833 @default.
- W2023756509 hasConceptScore W2023756509C185592680 @default.
- W2023756509 hasConceptScore W2023756509C197336794 @default.
- W2023756509 hasConceptScore W2023756509C21951064 @default.
- W2023756509 hasConceptScore W2023756509C2776923573 @default.
- W2023756509 hasConceptScore W2023756509C2779321498 @default.
- W2023756509 hasConceptScore W2023756509C2779938440 @default.
- W2023756509 hasConceptScore W2023756509C33923547 @default.
- W2023756509 hasConceptScore W2023756509C40875361 @default.
- W2023756509 hasConceptScore W2023756509C521977710 @default.
- W2023756509 hasConceptScore W2023756509C62520636 @default.
- W2023756509 hasConceptScore W2023756509C91881484 @default.
- W2023756509 hasIssue "20" @default.
- W2023756509 hasLocation W20237565091 @default.
- W2023756509 hasOpenAccess W2023756509 @default.
- W2023756509 hasPrimaryLocation W20237565091 @default.
- W2023756509 hasRelatedWork W1969836174 @default.
- W2023756509 hasRelatedWork W1994807294 @default.
- W2023756509 hasRelatedWork W2023756509 @default.
- W2023756509 hasRelatedWork W2027244224 @default.
- W2023756509 hasRelatedWork W2038461814 @default.
- W2023756509 hasRelatedWork W2086223393 @default.
- W2023756509 hasRelatedWork W2087395362 @default.
- W2023756509 hasRelatedWork W2528917393 @default.
- W2023756509 hasRelatedWork W3004720714 @default.
- W2023756509 hasRelatedWork W4213300914 @default.
- W2023756509 hasVolume "59" @default.
- W2023756509 isParatext "false" @default.
- W2023756509 isRetracted "false" @default.
- W2023756509 magId "2023756509" @default.
- W2023756509 workType "article" @default.