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- W2023756800 abstract "Two 1,2,4-diazaphospholide complexes of [Ti(η2-3,5-Ph2dp)4] and paramagnetic [Ti(η2-3,5-tBu2dp)3] were prepared by the reaction of tetrakis(dimethylamido)titanium(IV) with 3,5-diphenyl-1,2,4-diazaphophole, H[3,5-Ph2dp], or by the treatment of 3,5-tert-butyl-1,2,4-diazaphopholide potassium, K[3,5-tBu2dp], with titanium trichloride. Complexes can be viewed as the core of P(σ2λ3)-functionalized metallodendrimers, in which the metal atoms are exclusively η2(N,N) bonding to the 1,2,4-diazaphospholides while P atoms (σ2λ3) with electron lone pairs are located on the periphery of the molecules." @default.
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- W2023756800 date "2011-11-17" @default.
- W2023756800 modified "2023-09-23" @default.
- W2023756800 title "Synthesis and Structural Characterization of 1,2,4-Diazaphospholide Complexes of Titanium(IV) and Titanium(III)" @default.
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- W2023756800 doi "https://doi.org/10.1021/ic2021066" @default.
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