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- W2023763398 abstract "Reactions of NCCH2COOMe 1a and CH2(CN)2 1b with 2,4-dinitrofluorobenzene 2 at the presence of Et3 N result in deeply colored crystalline stable salts 4a,4b with anions that contain a system of conjugated bonds. Similar reaction of 2 with phosphorus-containing zwitterion 6 bearing ethoxy- and cyano-groups at the carbanion center is the first example of the reaction leading to the formation of P-zwitterion 9 with a negatively charged heptatriene moiety. This reaction proceeds via a new route of decomposition of the intermediate σ-complex 7 occurring with formation of ethylfluoroformate. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:108–115, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20267" @default.
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- W2023763398 date "2007-01-01" @default.
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- W2023763398 title "Reactions of carbanions with 2,4-dinitrofluorobenzene leading to stable heptatrienide moieties" @default.
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- W2023763398 doi "https://doi.org/10.1002/hc.20267" @default.
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