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- W2023766229 abstract "A novel fungicide, (-)(E)-1-(2,4-dichlorophenyl)-4, 4-dimethyl-2(1,2,4-triazol-1-yl)-1-penten-3-ol (S-3308 L) and its three optically active stereoisomers were labeled with carbon-14 at the triazole ring for use in the metabolic and environmental fate studies. 1,2,4-Triazole-14C (4) prepared from formamide-14C (3) was treated with bromopinacolone to give triazolylpinacolone-14C (5), which was condensed with 2,4-dichlorobenzaldehyde giving (Z)-ketone-14C (6). (Z)-Ketone-14C (6) was photoisomerized to (E)-ketone- 14C (7), which was reduced to racemic (Z)-S-3308- 14C (1) in 20% yield from 3. Reduction of 6 gave racemic (Z))S-3308-14C (2) in 23% field from 3. Optical resolution of both racemates 1 and 2 by a HPLC method with a chiral column gave (-)(E)-, (+)(E)-, (-)(Z)- and (+)(Z)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-[14C]-1-yl)-1-penten-3-ols (1a, 1b, 2a and 2b) in essentially Quantitative yields." @default.
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- W2023766229 date "1986-06-01" @default.
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- W2023766229 title "14C-labeling of a novel fungicide. I. Syntheses of optically active (E)-and (Z)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-[14C]-1-YL)-1-penten-3-OLS" @default.
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- W2023766229 doi "https://doi.org/10.1002/jlcr.2580230609" @default.
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