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- W2023771743 abstract "Abstract This paper aims at characterizing hydration behaviour and structural properties of a dioctahedral smectite (i.e. Wyoming montmorillonite), used in the context of naturel barrier for municipal waste disposal sites, and which is saturated by heavy metals cations coming from wastewater solution. Hydration of the 2+ , Pb 2+ , Zn 2+ , Co 2+ , Cd 2+ and Ni 2+ saturated specimens. There are heavy metal cations that are characterized by high natural abundance. The qualitative XRD investigation under room conditions (~ 35%RH) showed a similar hydration behaviour characterized by presence of three principal hydration states: 1 W, 2 W and 1 W-2 W (i.e. One, two and intermediate water layers hydration state, respectively). In order to highlight the specific hydration properties of each complex, we have studied by quantitative XRD analysis the hydration evolution under controlled relative humidity. Obtained result showed the possibility to distinguish between sample saturated with Na, Cu and Pb for high RH values (≈ 75%). For Ni, Zn, Cd and Co we have shown similar hydration behavior in all explored RH's range except the Ni 2+ cation which presents a homogeneous 3 W hydration state for 75%RH." @default.
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- W2023771743 date "2011-04-01" @default.
- W2023771743 modified "2023-10-16" @default.
- W2023771743 title "XRD investigations of hydrated homoionic montmorillonite saturated by several heavy metal cations" @default.
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- W2023771743 doi "https://doi.org/10.1016/j.desal.2010.12.018" @default.
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