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• W2023776490 abstract "Two novel coordination polymers incorporating mercury(II) iodide, [Hg (tmp)I2]n (1) (tmp=4,4′-trimethylene dipyridine) and [Hg(azobpy)I2]n (2) (azobpy=3,3′-azobispyridine), have been synthesized via the self-assembly reaction in solution. Their structures were characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Complex 1 is the first 1D wave-shaped adduct containing HgI2. Complex 2 is a 3D supramolecular framework constructed from HgI2–azobpy zigzag chains linked mutually through Hg⋯I interaction. The optical limiting effects were studied by Z-scan technology with an 8 ns-pulsed laser at 532 nm. Their limiting thresholds were determined to be 0.8 J cm−2 for 1 and 0.4 J cm−2 for 2, which are comparable to those of many heterothiometallates." @default.
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• W2023776490 date "2003-11-01" @default.
• W2023776490 modified "2023-09-23" @default.
• W2023776490 title "The syntheses, crystal structures and optical limiting effects of HgI2 adduct polymers bridged by bipyridyl-based ligands" @default.
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• W2023776490 doi "https://doi.org/10.1016/s0020-1693(03)00348-7" @default.
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