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- W2023778913 abstract "Abstract A homochiral bicyclic ketone having a pinguisane skeleton has been synthesised starting from homochiral methyl 3-[(1′ S ,6′ R )-1′,6′-dimethyl-2′-oxo-1-yl]propionate prepared from pulegone using phenylethylamine as a chiral auxiliary. The five-membered ring was constructed by the Hosomi–Sakurai reaction of the allylsilane derived from the ketone. This synthesis can be considered a formal synthesis of deoxopinguisone." @default.
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- W2023778913 date "2001-02-01" @default.
- W2023778913 modified "2023-09-23" @default.
- W2023778913 title "Synthesis of a homochiral ketone having a pinguisane skeleton using phenylethylamine as a chiral auxiliary: a formal total synthesis of deoxopinguisone" @default.
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- W2023778913 doi "https://doi.org/10.1016/s0957-4166(01)00041-6" @default.
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