Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023779242> ?p ?o ?g. }
- W2023779242 endingPage "445" @default.
- W2023779242 startingPage "436" @default.
- W2023779242 abstract "In this article we report a femtosecond time-resolved transient absorption study of a neutral organic mixed-valence (MV) compound with the aim to gain insight into its charge-transfer dynamics upon optical excitation. The back-electron transfer was investigated in five different solvents, toluene, dibutyl ether, methyl-tert-butyl ether (MTBE), benzonitrile and n-hexane. In the pump step, the molecule was excited at 760 nm and 850 nm into the intervalence charge-transfer band. The resulting transients can be described by two time constant. We assign one time constant to the rearrangement of solvent molecules in the charge-transfer state and the second time constant to back-electron transfer to the electronic ground state. Back-electron transfer rates range from 1.5 × 1012 s−1 in benzonitrile through 8.3 × 1011 s−1 in MTBE, around 1.6 × 1011 s−1 in dibutylether and toluene and to 3.8 × 109 s−1 in n-hexane." @default.
- W2023779242 created "2016-06-24" @default.
- W2023779242 creator A5027735051 @default.
- W2023779242 creator A5029830318 @default.
- W2023779242 creator A5055196359 @default.
- W2023779242 creator A5072286903 @default.
- W2023779242 creator A5078054639 @default.
- W2023779242 creator A5090393665 @default.
- W2023779242 date "2008-05-01" @default.
- W2023779242 modified "2023-10-03" @default.
- W2023779242 title "Femtosecond dynamics of electron transfer in a neutral organic mixed-valence compound" @default.
- W2023779242 cites W1512361887 @default.
- W2023779242 cites W1644375502 @default.
- W2023779242 cites W1835764176 @default.
- W2023779242 cites W1963721326 @default.
- W2023779242 cites W1964761757 @default.
- W2023779242 cites W1969819843 @default.
- W2023779242 cites W1972476246 @default.
- W2023779242 cites W1982183246 @default.
- W2023779242 cites W1985738873 @default.
- W2023779242 cites W1985889445 @default.
- W2023779242 cites W1987570795 @default.
- W2023779242 cites W1988718742 @default.
- W2023779242 cites W1994538342 @default.
- W2023779242 cites W1994710354 @default.
- W2023779242 cites W1998112271 @default.
- W2023779242 cites W1999449827 @default.
- W2023779242 cites W2002164208 @default.
- W2023779242 cites W2005224133 @default.
- W2023779242 cites W2012116438 @default.
- W2023779242 cites W2016728813 @default.
- W2023779242 cites W2017216815 @default.
- W2023779242 cites W2022205840 @default.
- W2023779242 cites W2023665942 @default.
- W2023779242 cites W2026154892 @default.
- W2023779242 cites W2032202937 @default.
- W2023779242 cites W2036036568 @default.
- W2023779242 cites W2041565129 @default.
- W2023779242 cites W2042984582 @default.
- W2023779242 cites W2054913298 @default.
- W2023779242 cites W2054947925 @default.
- W2023779242 cites W2055275145 @default.
- W2023779242 cites W2058114908 @default.
- W2023779242 cites W2058164610 @default.
- W2023779242 cites W2059400512 @default.
- W2023779242 cites W2060492750 @default.
- W2023779242 cites W2062395549 @default.
- W2023779242 cites W2065701683 @default.
- W2023779242 cites W2073624912 @default.
- W2023779242 cites W2074632248 @default.
- W2023779242 cites W2076040523 @default.
- W2023779242 cites W2077306024 @default.
- W2023779242 cites W2085063736 @default.
- W2023779242 cites W2089662946 @default.
- W2023779242 cites W2090668262 @default.
- W2023779242 cites W2117888126 @default.
- W2023779242 cites W2129384172 @default.
- W2023779242 cites W2137213267 @default.
- W2023779242 cites W2138289499 @default.
- W2023779242 cites W2166636576 @default.
- W2023779242 cites W2167846329 @default.
- W2023779242 doi "https://doi.org/10.1016/j.chemphys.2007.11.022" @default.
- W2023779242 hasPublicationYear "2008" @default.
- W2023779242 type Work @default.
- W2023779242 sameAs 2023779242 @default.
- W2023779242 citedByCount "16" @default.
- W2023779242 countsByYear W20237792422012 @default.
- W2023779242 countsByYear W20237792422014 @default.
- W2023779242 countsByYear W20237792422015 @default.
- W2023779242 countsByYear W20237792422016 @default.
- W2023779242 countsByYear W20237792422019 @default.
- W2023779242 countsByYear W20237792422021 @default.
- W2023779242 countsByYear W20237792422022 @default.
- W2023779242 crossrefType "journal-article" @default.
- W2023779242 hasAuthorship W2023779242A5027735051 @default.
- W2023779242 hasAuthorship W2023779242A5029830318 @default.
- W2023779242 hasAuthorship W2023779242A5055196359 @default.
- W2023779242 hasAuthorship W2023779242A5072286903 @default.
- W2023779242 hasAuthorship W2023779242A5078054639 @default.
- W2023779242 hasAuthorship W2023779242A5090393665 @default.
- W2023779242 hasConcept C113196181 @default.
- W2023779242 hasConcept C120665830 @default.
- W2023779242 hasConcept C121332964 @default.
- W2023779242 hasConcept C123669783 @default.
- W2023779242 hasConcept C139932579 @default.
- W2023779242 hasConcept C167735695 @default.
- W2023779242 hasConcept C168900304 @default.
- W2023779242 hasConcept C178790620 @default.
- W2023779242 hasConcept C181500209 @default.
- W2023779242 hasConcept C184779094 @default.
- W2023779242 hasConcept C185592680 @default.
- W2023779242 hasConcept C2778142098 @default.
- W2023779242 hasConcept C2779953769 @default.
- W2023779242 hasConcept C32891209 @default.
- W2023779242 hasConcept C41625074 @default.
- W2023779242 hasConcept C520434653 @default.
- W2023779242 hasConcept C55493867 @default.
- W2023779242 hasConcept C62520636 @default.