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- W2023782657 abstract "Methodology has been developed for the general synthesis of optically active beta-amino acid N-carboxyanhydrides (beta-NCAs) through cyclization of N(beta)-Boc or N(beta)-Cbz beta-amino acids using phosphorus tribromide. The formation of beta-NCAs was confirmed by spectroscopy as well as an X-ray structural determination of beta-homoalanine-N-carboxyanhydride. The beta-NCA molecules could be polymerized in good yield to give optically active poly(beta-peptides) that adopt stable chiral conformations in solution. For example, helical oligo(L-beta-homophenylalanine) was synthesized by polymerization of L-beta-homophenylalanine-N-carboxyanhydride." @default.
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- W2023782657 date "2000-06-01" @default.
- W2023782657 modified "2023-10-12" @default.
- W2023782657 title "Synthesis of Optically Active β-Amino Acid <i>N</i>-Carboxyanhydrides" @default.
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- W2023782657 doi "https://doi.org/10.1021/ol000122w" @default.
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