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- W2023791371 abstract "At 300 K and in the coverage regime (0<θ<13) bromine chemisorbs rapidly on Pd(111); the sticking probability and dipole moment per adatom remain constant at 0.8 ± 0.2 and 1.2 D, respectively. This stage is marked by the appearance of a √3 structure: desorption occurs exclusively as atomic Br. At higher coverages, desorption of molecular Br2 begins (desorption energy ∼130 kJ mol−1) as does the nucleation and growth of PdBr2 on the surface. This latter stage is signalled by the appearance of a √2 LEED pattern and the observation of PdBr2 as a desorption product (desorption energy ∼37 kJ mol−1). Some PdBr2 is also lost by surface decomposition and subsequent evaporation of atomic Br. The data indicate that the transition state to Br adatom desorption is localised and that PdBr2(a) ⇄ Br(a) interconversion occurs; these surface species do not appear to be in thermodynamic equilibrium during the desorption process." @default.
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- W2023791371 date "1982-02-01" @default.
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- W2023791371 title "Surface chemistry of the metal-halogen interface: Bromine chemisorption and dibromide formation on palladium (111)" @default.
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- W2023791371 doi "https://doi.org/10.1016/0039-6028(82)90659-8" @default.
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