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- W2023793802 abstract "The reactions of ferulic acid and its derivatives with hydrogen peroxide and peracetic acid in lignin-retaining bleaching conditions have been investigated to determine their susceptibility to oxidative degradation. The conjugated side chain of ferulic acid and its etherified or esterified derivative was shown to be fairly stable, especially to hydrogen peroxide. The major reaction was trans−cis isomerization that possibly involved a radical mechanism but did not cause bond cleavage. The peracetic acid reaction increased the rate of trans−cis isomerization and was also accompanied by a minor cleavage of the side chain. Esterification did not have a substantial effect on the reactivity of ferulic acid, but 4-O-etherification significantly stabilized it against these two oxidants. By contrast, aldehyde substitution tremendously enhanced the susceptibility of the cinnamyl side chain to oxidative degradation, as evidenced by an intensive degradation of coniferaldehyde. Keywords: Hydrogen peroxide; peracetic acid; oxidation; ferulic acid; ferulate; coniferaldehyde" @default.
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- W2023793802 date "1999-07-14" @default.
- W2023793802 modified "2023-09-23" @default.
- W2023793802 title "Reactivity of Ferulic Acid and Its Derivatives toward Hydrogen Peroxide and Peracetic Acid" @default.
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- W2023793802 doi "https://doi.org/10.1021/jf9902494" @default.
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