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• W2023794102 startingPage "1341" @default.
• W2023794102 abstract "A stereoselective synthesis of agelastatin A, a potent cytotoxin and inhibitor of osteopontin (OPN)-mediated neoplastic transformations, has been accomplished in 14 steps (12 operations) with an approximate overall yield of 8%. Notable features of this route include the direct manner in which the pyrroloketopiperazine A-ring of the target is generated and the efficient employment of a trichloroacetamide, introduced through Overman rearrangement, as a protecting group, pendant nucleophile, and latent urea." @default.
• W2023794102 created "2016-06-24" @default.
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• W2023794102 creator A5036908323 @default.
• W2023794102 date "2009-02-19" @default.
• W2023794102 modified "2023-10-16" @default.
• W2023794102 title "Total Synthesis of (±)-Agelastatin A, A Potent Inhibitor of Osteopontin-Mediated Neoplastic Transformations" @default.
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• W2023794102 doi "https://doi.org/10.1021/ol900133v" @default.
• W2023794102 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2671850" @default.
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