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• W2023795053 abstract "We report the discovery of an antiferromagnetic coupling of the magnetic moment of chromium(II) tetraphenyl-porphyrin (CrTPP) molecules to the magnetization of the clean ferromagnetic Co(001) substrate. We assign this unusual molecule-substrate exchange coupling to the less than half-filled chromium $3d$ orbitals interacting with Co valence band electrons via porphyrin-ligand molecular orbitals. X-ray magnetic circular dichroism, x-ray photoelectron spectroscopy, and scanning tunneling microscopy are combined with $mathrm{DFT}+U$ calculations and provide evidence for a surprising type of antiferromagnetic ${90}^{ensuremath{circ}}$ indirect magnetic exchange coupling." @default.
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• W2023795053 date "2014-12-10" @default.
• W2023795053 modified "2023-09-26" @default.
• W2023795053 title "Antiferromagnetic coupling of Cr-porphyrin to a bare Co substrate" @default.
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• W2023795053 doi "https://doi.org/10.1103/physrevb.90.220404" @default.
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