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- W2023796635 abstract "The effects of an external magnetic field (H = 2000 G) on photogenerated geminate (G) and random (F) pairs of chlorophyll a radical cation and p-benzoquinone radical anion in viscous 1,3-propanediol have been measured: αG = 8±1%, αF = − 7±2%. The results have been used for calculation of the probability of the triplet pair S-T evolution and subsequent reaction φ ≈ 0.37 and the fraction of triplet pairs unable to react due to application of a magnetic field β ≈ 0.14. The validity of the estimates has been verified through independent experiments in which the cage effects under photochemical generation of these radical ions have been determined. The role of the hfi and relaxation mechanisms in the S-T evolution of radical pairs in viscous liquids and the differences in the magnetic properties of the G- and F-pairs are discussed." @default.
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- W2023796635 date "1986-03-01" @default.
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- W2023796635 title "Magnetic field effect on the geminate and random radical pairs under reversible photooxidation of chlorophyll a in 1,3-propanediol" @default.
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- W2023796635 doi "https://doi.org/10.1016/0009-2614(86)85059-x" @default.
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