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- W2023802643 abstract "A series of isoxazolo[60]fullerenes has been prepared in one pot from aldoximes under microwave irradiation. Several donors and acceptors were used as substituents. The absorption and emission spectra of these compounds in polar solvents suggest a weak charge-transfer interaction between the oxygen atom of the isoxazoline moiety and the C60 cage, as well as a stronger interaction between the donor and the fullerene cage when the attached groups are p-N,N-dimethylaniline or ferrocene. The electrochemical properties of the compounds were investigated and they show the same or better acceptor character than C60 in all cases. Theoretical calculations support the results obtained. Solvent effects in the 1H NMR spectra have been determined and provide useful information concerning the polarization of dyads." @default.
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- W2023802643 date "2000-11-18" @default.
- W2023802643 modified "2023-10-02" @default.
- W2023802643 title "Synthesis and Properties of Isoxazolo[60]fullerene−Donor Dyads" @default.
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- W2023802643 doi "https://doi.org/10.1021/jo0010532" @default.
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