FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023802709> ?p ?o ?g. }

• W2023802709 endingPage "310" @default.
• W2023802709 startingPage "298" @default.
• W2023802709 abstract "Several conflicting reports have suggested that heat capacities and the thermodynamic properties of materials change as their particle size decreases into the nanoscale. To further investigate this, we have measured the constant pressure heat capacities of three 7 nm TiO2 anatase samples containing varying amounts of surface-adsorbed water using a combination of adiabatic and semi-adiabatic calorimetric methods. These samples have a high degree of chemical, phase, and size purity determined by rigorous characterization. Molar heat capacities were measured from T = (0.5 to 320) K, and data were fit to a sum of theoretical functions in the low temperature (T < 15 K) range, orthogonal polynomials in the mid temperature range (10 > T > 75 K), and a combination of Debye and Einstein functions in the high temperature range (T > 35 K). These fits were used to generate Cp,m°, Δ0TSm°, Δ0THm°, and φm° values at smoothed temperatures between (0.5 and 300) K for all hydrated samples. Standard molar entropies at T = 298.15 K were calculated to be 73.868, 66.072, and 63.845 J · K−1 · mol−1 all with a standard uncertainty of 0.002·Δ0TSm° for samples TiO2 · 0.677H2O, TiO2 · 0.532H2O, and TiO2 · 0.379H2O, respectively. These and other thermodynamic values were then corrected for water content to yield bare nano-TiO2 thermodynamic properties at T = 298.15 K, and we show that the resultant thermodynamic properties of anhydrous TiO2 anatase nanoparticles equal those of bulk TiO2 anatase within experimental uncertainty. Thus we show quantitatively that the difference in thermodynamic properties between bulk and nano-TiO2 must be attributed to surface adsorbed water." @default.
• W2023802709 created "2016-06-24" @default.
• W2023802709 creator A5003554239 @default.
• W2023802709 creator A5014245487 @default.
• W2023802709 creator A5015089175 @default.
• W2023802709 creator A5040583443 @default.
• W2023802709 creator A5042237475 @default.
• W2023802709 creator A5064949533 @default.
• W2023802709 creator A5065570154 @default.
• W2023802709 creator A5074375770 @default.
• W2023802709 date "2015-02-01" @default.
• W2023802709 modified "2023-09-26" @default.
• W2023802709 title "Heat capacity and thermodynamic functions of nano-TiO2 anatase in relation to bulk-TiO2 anatase" @default.
• W2023802709 cites W1976677541 @default.
• W2023802709 cites W1986440718 @default.
• W2023802709 cites W1990249941 @default.
• W2023802709 cites W1991498626 @default.
• W2023802709 cites W1996227879 @default.
• W2023802709 cites W1999848155 @default.
• W2023802709 cites W2001377273 @default.
• W2023802709 cites W2003175485 @default.
• W2023802709 cites W2009755186 @default.
• W2023802709 cites W2019129846 @default.
• W2023802709 cites W2019387305 @default.
• W2023802709 cites W2024807510 @default.
• W2023802709 cites W2025348560 @default.
• W2023802709 cites W2025762213 @default.
• W2023802709 cites W2042661013 @default.
• W2023802709 cites W2043864759 @default.
• W2023802709 cites W2047241238 @default.
• W2023802709 cites W2047395629 @default.
• W2023802709 cites W2062009957 @default.
• W2023802709 cites W2067484220 @default.
• W2023802709 cites W2070556457 @default.
• W2023802709 cites W2070717205 @default.
• W2023802709 cites W2074301732 @default.
• W2023802709 cites W2074330257 @default.
• W2023802709 cites W2092226475 @default.
• W2023802709 cites W2093407510 @default.
• W2023802709 cites W2095174812 @default.
• W2023802709 cites W2099606293 @default.
• W2023802709 cites W2105646329 @default.
• W2023802709 cites W2110540540 @default.
• W2023802709 cites W2123977219 @default.
• W2023802709 cites W2124625956 @default.
• W2023802709 cites W2139906905 @default.
• W2023802709 cites W2169967185 @default.
• W2023802709 cites W2322723320 @default.
• W2023802709 cites W2336910392 @default.
• W2023802709 cites W2339293777 @default.
• W2023802709 cites W2952238583 @default.
• W2023802709 cites W320425042 @default.
• W2023802709 cites W4248309453 @default.
• W2023802709 doi "https://doi.org/10.1016/j.jct.2014.07.025" @default.
• W2023802709 hasPublicationYear "2015" @default.
• W2023802709 type Work @default.
• W2023802709 sameAs 2023802709 @default.
• W2023802709 citedByCount "24" @default.
• W2023802709 countsByYear W20238027092015 @default.
• W2023802709 countsByYear W20238027092016 @default.
• W2023802709 countsByYear W20238027092017 @default.
• W2023802709 countsByYear W20238027092018 @default.
• W2023802709 countsByYear W20238027092019 @default.
• W2023802709 countsByYear W20238027092020 @default.
• W2023802709 countsByYear W20238027092021 @default.
• W2023802709 countsByYear W20238027092022 @default.
• W2023802709 crossrefType "journal-article" @default.
• W2023802709 hasAuthorship W2023802709A5003554239 @default.
• W2023802709 hasAuthorship W2023802709A5014245487 @default.
• W2023802709 hasAuthorship W2023802709A5015089175 @default.
• W2023802709 hasAuthorship W2023802709A5040583443 @default.
• W2023802709 hasAuthorship W2023802709A5042237475 @default.
• W2023802709 hasAuthorship W2023802709A5064949533 @default.
• W2023802709 hasAuthorship W2023802709A5065570154 @default.
• W2023802709 hasAuthorship W2023802709A5074375770 @default.
• W2023802709 hasBestOaLocation W20238027091 @default.
• W2023802709 hasConcept C109663097 @default.
• W2023802709 hasConcept C113196181 @default.
• W2023802709 hasConcept C121332964 @default.
• W2023802709 hasConcept C133347239 @default.
• W2023802709 hasConcept C161790260 @default.
• W2023802709 hasConcept C178790620 @default.
• W2023802709 hasConcept C185592680 @default.
• W2023802709 hasConcept C2777402863 @default.
• W2023802709 hasConcept C39353612 @default.
• W2023802709 hasConcept C60205243 @default.
• W2023802709 hasConcept C65165184 @default.
• W2023802709 hasConcept C97355855 @default.
• W2023802709 hasConceptScore W2023802709C109663097 @default.
• W2023802709 hasConceptScore W2023802709C113196181 @default.
• W2023802709 hasConceptScore W2023802709C121332964 @default.
• W2023802709 hasConceptScore W2023802709C133347239 @default.
• W2023802709 hasConceptScore W2023802709C161790260 @default.
• W2023802709 hasConceptScore W2023802709C178790620 @default.
• W2023802709 hasConceptScore W2023802709C185592680 @default.
• W2023802709 hasConceptScore W2023802709C2777402863 @default.
• W2023802709 hasConceptScore W2023802709C39353612 @default.
• W2023802709 hasConceptScore W2023802709C60205243 @default.

• next