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- W2023806475 abstract "As a model for the tritium labeling of peptides, the catalytic dehalogenation of N-Acetyl-L-4-chloro- and N-Acetyl-L-4-iodo-phenylalanine amide was investigated in the presence of deuterium, using different reaction conditions. A catalyst-mediated transfer of the solvent-hydrogen to the substrate was found to be the most probable reason for the exchange of halogen by hydrogen instead of deuterium. This unwanted transter was most intensive in the presence of water. An incorporation of additional deuterium besides the 4-position of phenylalanine takes place simultaneously with the dehalogenation especially of the chloro derivative." @default.
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- W2023806475 date "1986-09-01" @default.
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- W2023806475 title "Catalytic dehalogenation of N-acetyl-L-4-chloro- and N-acetyl-L-4-iodophebylalanine amide in the presence of deuterium" @default.
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- W2023806475 doi "https://doi.org/10.1002/jlcr.2580230904" @default.
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