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- W2023806740 abstract "Oxidation of methane over yttria/zirconia mixed oxide shows two parallel oxidation pathways, i.e. partial oxidation to CO+H2+H2O and full oxidation to CO2+2H2O. Both reactions proceed via a Mars van Krevelen mechanism with first order kinetics for methane and oxygen and are retarded by water. A mechanism is suggested in which methane is homolitically dissociated over O−(s) sites and via the formation and decomposition of a formaldehyde precursor reacted to CO, H2 and H2O. In parallel, CO2 is obtained from decomposition of bicarbonate that is formed via further oxidation of dioxymethylene." @default.
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- W2023806740 date "1998-11-01" @default.
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- W2023806740 title "On the reaction mechanism for methane partial oxidation over yttria/zirconia" @default.
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- W2023806740 doi "https://doi.org/10.1016/s0920-5861(98)00330-7" @default.
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