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- W2023809068 abstract "Sr2(MgMo)2O6−δ and materials of nominal compositions with increased and decreased Mo content were synthesized and their stability and catalytic activity towards CH4 oxidation characterized under solid oxide fuel cell (SOFC) anode conditions. Sr2(MgMo)2O6−δ was synthesized as a double perovskite. Materials with increased Mo content formed a mixture of the double perovskite Sr2MgMoO6−δ and the single perovskite SrMoO3, after synthesis in H2, with the amount of SrMoO3 increasing with increasing Mo content. SrMoO3 is unstable in air and slowly oxidized to the scheelite-structured impurity SrMoO4. All compositions decomposed to Mo, MgO and SrO in dry 20% CH4/N2 at temperatures ≥ 850 °C. CH4 reaction rates were catalytically limited with measured rates significantly lower than for La0.75Sr0.25Cr0.5Mn0.5O3-δ. Rates increased by 1–2 orders of magnitude when 2 wt-% of Pt was added to the surface." @default.
- W2023809068 created "2016-06-24" @default.
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- W2023809068 date "2011-01-01" @default.
- W2023809068 modified "2023-10-10" @default.
- W2023809068 title "On the methane oxidation activity of Sr2(MgMo)2O6-δ: a potential anode material for direct hydrocarbon solid oxide fuel cells" @default.
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- W2023809068 doi "https://doi.org/10.1039/c1jm10523j" @default.
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