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• W2023830006 endingPage "637" @default.
• W2023830006 startingPage "630" @default.
• W2023830006 abstract "A series of new sterically hindered N,N′-polymethylenebis(3,5-tBu2salicylaldimine) ligands (H2Lx) VO(IV) complexes, [VO{(2-O-3,5-tBu2C6H2)CHN-R-NCH-(3,5-tBu2-C6H2O-2)] (X), where R = –(CH2)3– (3), –(CH2)4– (4), –(CH2)5– (5), –(CH2)6– (6) and –CH2C(CH3)2CH2– (7) and early reported –(CH2)2– (1) and –CH2CH(CH3)– (2), has been synthesized and characterized by spectroscopic (IR, UV/vis, 1H NMR, EPR), electrochemical and magnetic susceptibility measurements. Complexes 1–7 are described a trigonal distorted pyramids. All seven compounds give nearly the same parallel hyperfine coupling constant (Az) regardless that the geometry of VO(IV) changes from square pyramidal to trigonal distorted pyramids. Chemical oxidation of 1–7 by one equiv Ce(IV) leads to the formation of stable [VO(V)Lx]+ complexes. Cyclic voltammograms of 2–6 in DMSO along with a quasi-reversible VO(IV)/VO(V) redox couple also showed irreversible phenolate/phenoxyl responses. Each 1 and 7 shows only one reversible VO(IV) centered oxidation waves. Chemical oxidation of H2Lx forms the stable [H2Lx]+ radical species." @default.
• W2023830006 created "2016-06-24" @default.
• W2023830006 creator A5005045778 @default.
• W2023830006 creator A5018561711 @default.
• W2023830006 creator A5048480063 @default.
• W2023830006 creator A5061116810 @default.
• W2023830006 date "2010-10-01" @default.
• W2023830006 modified "2023-09-27" @default.
• W2023830006 title "Synthesis, spectroscopic characterization and reactivity studies of oxovanadium(IV) complexes with bulky N,N′-polymethylenebis(3,5-tBu2salicylaldimine) ligands" @default.
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• W2023830006 doi "https://doi.org/10.1016/j.saa.2010.06.040" @default.
• W2023830006 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20674475" @default.
• W2023830006 hasPublicationYear "2010" @default.
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