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• W2023834029 startingPage "124" @default.
• W2023834029 abstract "Previously reported values of pKa and K(HA2-) of sulfuric (first step) and nitric acids in acetonitrile derived from spectrophotometric indicator data have been revised. The revised values are 8.04, 2.7 × 103 mol-1 dm3 and 10.59, 1.2 × 103 mol-1 dm3, respectively. Both Ka and K(HA2-) of sulfuric acid are some 1.7 times smaller than those reported from potentiometric glass electrode data. An estimate of KaK(HA2-) of sulfuric acid was made from simultaneous spectrophotometric nitroaniline indicator and electrolytic conductivity measurements in solutions allowed to stand for various times. The glass electrode was used in mixtures of nitric acid and tetraethylammonium nitrate, pKa and K(HA2-) being 10.53 and 1.15 × 103 mol-1 dm3, respectively. The homoconjugation constant was verified from the increase in solubility of sodium nitrate in the presence of nitric acid. The protonation constant of aniline, 1010.57 mol-1 dm3, was determined spectrophotometrically in aniline−anilinium perchlorate mixtures with p,p‘-dimethylaminoazobenzene and found to be in excellent agreement with the literature value." @default.
• W2023834029 created "2016-06-24" @default.
• W2023834029 creator A5031116363 @default.
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• W2023834029 date "1998-11-17" @default.
• W2023834029 modified "2023-09-24" @default.
• W2023834029 title "Dissociation Constant, <i>K</i>_a, and Stability Constant, <i>K</i>(HA₂^-), of the 1:1 Homoconjugate of Sulfuric and Nitric Acids in Acetonitrile at 298.1 K. Revised Values" @default.
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• W2023834029 doi "https://doi.org/10.1021/je9801922" @default.
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