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- W2023836178 abstract "Multifunctional microgel-core star polymers with ruthenium catalysts are designed as catalyst-bearing nanoreactors to improve activity, controllability, and functionality tolerance in living radical polymerization. Multifunctional ligands are efficiently incorporated into the core of star polymers by sequential tandem procedures: 1) ruthenium-catalyzed living radical polymerization, 2) in situ core hydrogenation, and 3) core-ruthenium removal. Typically, the star polymer ligands comprising multiple phosphines and amines within the core cooperatively enclose a ruthenium complex (>100 per core). As a result, the in-core pseudo hetero P,N-chelation of the ruthenium complexes not only showed high activity for methyl methacrylate but also high tolerance to unprotected methacrylic acid." @default.
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- W2023836178 date "2012-04-23" @default.
- W2023836178 modified "2023-10-14" @default.
- W2023836178 title "Efficient and Robust Star Polymer Catalysts for Living Radical Polymerization: Cooperative Activation in Microgel-Core Reactors" @default.
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- W2023836178 doi "https://doi.org/10.1002/marc.201200045" @default.
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