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- W2023841458 abstract "The regio-, diastereo-, and π-facial selective Lewis acid mediated Diels–Alder reactions of cis/trans-3-butadienyl-2-azetidinones with unsymmetrical dienophiles viz. methyl acrylate, dimethyl fumarate, and acrolein leading to the synthesis of diastereomerically pure and biologically potent 1,3,4-trisubstituted-2-azetidinones are reported. Theoretical calculations at HF/6-31G∗∗ and 6-31G∗∗/DFT levels have been performed to support the observed π-facial selectivity. The formation of diastereomerically pure ‘endo’ adducts is supported by the X-ray diffraction studies." @default.
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- W2023841458 date "2008-07-01" @default.
- W2023841458 modified "2023-10-15" @default.
- W2023841458 title "Regio- and π-facial selective Lewis acid interceded Diels–Alder reactions of α-dienyl-β-lactams: an indepth analysis" @default.
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- W2023841458 doi "https://doi.org/10.1016/j.tet.2008.04.087" @default.
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