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• W2023841553 abstract "Sugar 1,4-lactones reacted with hexamethylphosphorous triamide-tetrachloromethane to give dichloroolefins in one step. These compounds are versatile intermediates. Treatment of these 1,1-dichloro-1,1-dideoxy-3,4,-O-isopropylidene derivatives with lithium diisopropylamide gave the corresponding 4-deoxy-3-ulo derivatives. Reduction of the dichloromethylene group gave a methyl group with high stereospecifity. This opens the way to a set of 2,5-anhydro-1-deoxyalditols." @default.
• W2023841553 created "2016-06-24" @default.
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• W2023841553 date "1987-12-01" @default.
• W2023841553 modified "2023-10-18" @default.
• W2023841553 title "Dichloromethylenation of 1,4-lactones. A new access to 1-deoxy-1-C-methyl-C-glycosyl compounds" @default.
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• W2023841553 doi "https://doi.org/10.1016/s0008-6215(00)90875-9" @default.
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