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• W2023862409 endingPage "89" @default.
• W2023862409 startingPage "81" @default.
• W2023862409 abstract "Zeolite T membranes were synthesized from clear solutions with a molar composition of SiO2: Al2O3: Na2O: K2O: H2O = 1: 0.015: 0.25: 0.08: 30 on seeded mullite tubes using nano-sized (∼100 nm) and micro-sized (∼4000 nm) zeolite T seeds, respectively. It was found that a crystal growth behavior was strongly dependent on synthesis temperature, seeding and silica source. Zeolite T crystals fast grew onto the nano-sized-zeolite-T seeded supports, leading to the formation of a (00l)&(h0l)-oriented top crystal layer at synthesis temperatures of 373 and 423 K, respectively. The same oriented crystal top layer was also formed on the micro-sized-zeolite T seeded mullite tube at 423 K. The oriented zeolite T membranes displayed good PV performance for water over organic mixtures. For example, the highest water/i-propanol separation factor of 13,000 with a high flux of 2.50 kg m−2 h−1 for a feed concentration of 10 wt% water at 348 K was obtained through the zeolite T membrane synthesized on the micro-sized-zeolite-T seeded tube at 423 K. Twelve membranes prepared under optimized synthesis conditions showed high flux and selectivity with low deviations, indicating the membrane synthesis had good reproducibility. The as-synthesized zeolite T membranes also revealed good hydrothermal and acidic (at pH = 3) stabilities." @default.
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• W2023862409 date "2013-07-01" @default.
• W2023862409 modified "2023-09-28" @default.
• W2023862409 title "Synthesis of oriented zeolite T membranes from clear solutions and their pervaporation properties" @default.
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• W2023862409 doi "https://doi.org/10.1016/j.micromeso.2013.02.019" @default.
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