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- W2023862600 abstract "Abstract The high-temperature metal-insulator transition in Cr-doped V 2 O 3 , (V 1− x Cr x ) 2 O 3 , was investigated by TEM at a composition x = 0.006. Boundaries between the metallic phase and the insulator phase were observed between room temperature and 150°C by both heating and cooling and their crystallographic features were investigated. Boundaries are low-index planes and their orientations are such that the change of dimension by the transition in the direction parallel to the specimen surface is zero. This indicates that the orientation of the boundary is determined by the condition of minimum strain energy. Misfit dislocations parallel to the specimen surface were found to exist under this condition. The motion of the boundaries is fast, but the boundaries can be trapped by defects or at those places where the area of boundaries becomes minimum. The observation is consistent with the existence of the temperature hysteresis of the transition and the discontinuous change of the resistivity-temperature curve of this transition." @default.
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- W2023862600 date "1982-11-01" @default.
- W2023862600 modified "2023-09-25" @default.
- W2023862600 title "TEM observation of the high-temperature metal-insulator transition in Cr-doped V2O3" @default.
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- W2023862600 doi "https://doi.org/10.1016/0022-4596(82)90280-8" @default.
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