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- W2023868894 abstract "De novo synthesis of the natural products benzosceptrin C (7) and nagelamide H (8) was achieved using cell-free enzyme preparations from the marine sponges Agelas sceptrum and Stylissa caribica employing synthetic 7-(15)N-oroidin. These studies provide direct experimental evidence to support the long-standing, but untested, hypothesis that oroidin is a precursor to more complex pyrrole-aminoimidazole alkaloids, such as the sceptrins, benzosceptrins, and nagelamides. In addition, a new nagelamide, didebromonagelamide A (5b), was isolated from S. caribica, representing the first report of a nagelamide-like compound from the Caribbean." @default.
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- W2023868894 date "2012-03-28" @default.
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- W2023868894 title "De Novo Synthesis of Benzosceptrin C and Nagelamide H from 7-<sup>15</sup>N-Oroidin: Implications for Pyrrole–Aminoimidazole Alkaloid Biosynthesis" @default.
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- W2023868894 doi "https://doi.org/10.1021/np300051k" @default.
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