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- W2023874898 abstract "A series of four tripodal ligands L1–4 were prepared by the reaction of 9-(2-hydroxy)phenylimino-4,5-diazafluorene with 1,3,5-tris(bromomethyl)benzene, 1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene, tris(2-chloroethyl)amine hydrochloride, and pentaerythrityl tetratosylate, respectively, in DMF solution under nitrogen. For each ligand, Ru(II) complexes were prepared by refluxing Ru(bipy)2Cl2 · 2H2O and ligand in 2-methoxyethanol. Photophysical behaviors of these Ru(II) complexes have been investigated by UV-Vis absorption and luminescence spectrometry. They display metal-to-ligand charge transfer absorption at 442 nm in MeCN solution at room temperature and emission at 574 nm in EtOH–MeOH (4 : 1, v/v) glassy matrix at 77 K. Electrochemical studies of the Ru(II) complexes show one Ru(II)-centered oxidation at 1.33 V and three ligand-centered reductions." @default.
- W2023874898 created "2016-06-24" @default.
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- W2023874898 date "2011-12-21" @default.
- W2023874898 modified "2023-09-24" @default.
- W2023874898 title "Synthesis, photophysical, and electrochemical properties of a new family of trinuclear Ru(II) polypyridine complexes" @default.
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- W2023874898 doi "https://doi.org/10.1080/00958972.2011.646998" @default.
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