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- W2023877025 abstract "The molecular Zeeman effect is reported for 3-oxetanone and 3-methylene oxetane at fields near 20000 G. The results for 3-oxetanone are molecular g-values: gaa = −0.1059 ± 0.0008, gbb = −0.0581 ± 0.0004,gcc = −0.0437 ± 0.0004, magnetic susceptibility anisotropies:2xaa -xbb - xcc = (9.6±0.5) x 10−6 erg/G2mole, 2xbb - xaa - xcc = −(7.8±0.6) x 10−6 erg/G2mole, and molecular quadrupole moments: Qaa = −(12.8±0.8) x 10−26 esu cm,Qbb = (7.9±0.8) x 10−26 esu cm, and Qcc = (4.9±0.8) x 10−26 esu cm. For 3-methylene oxetane, the results are gaa = −0.0510 ± 0.0018, gbb = −0.0435 ± 0.0010, gcc = −0.0313 ± 0.0010, 2xaa - xbb - xcc = −(10.9±0.5) x 10−6 erg/G2 mole, 2xbb - xaa - xcc = (2.3±0.9) x 10−6 erg/G2 mole, Qaa = -⊂5.4±1.0) x 10−26 esu cm, Qbb = (5.1 ± 1.2) x 10−26 esu cm, and Qcc = (0.2±1.5) x 10−26 esu cm. The bulk magnetic susceptibility for 3-oxetanone was measured to be x = 1/2 (xaa+xbb+xcc) = −(30.6±1.5) x 10−6 erg/G2 mole. The out-of-plane minus average in-plane magnetic-susceptibility anisotropies in four-membered rings show larger paramagnetism than predicted on the basis of localized group susceptibility anisotropies. This effect is discussed and a possible explanation presented." @default.
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- W2023877025 date "1973-01-01" @default.
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- W2023877025 title "Molecular Zeeman effect of 3-oxetanone and 3-methylene oxetane, and the comparison of the magnetic-susceptibility anisotropies, molecular quadrupole moments, and other magnetic parameters with other four-membered rings" @default.
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- W2023877025 doi "https://doi.org/10.1016/0301-0104(73)87016-8" @default.
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