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- W2023883460 abstract "We have examined the acidic properties of a SiO2-on-Al2O3 monolayer catalyst by 31P NMR of adsorbed tricyclohexylphosphine and triphenylphosphine. These large probe molecules permit the assessment of steric effects, by comparison with trimethylphosphine, and reveal differences in acid strengths of surface sites. We find that there are significant constraints to accessing Lewis sites, but not Brønsted sites. The concentration of strong Brønsted sites is slightly less than half of the total concentration of Brønsted sites." @default.
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- W2023883460 title "Acid Sites on SiO<sub>2</sub>−Al<sub>2</sub>O<sub>3</sub> Monolayer Catalysts: <sup>31</sup>P NMR Probes of Strength and Accessibility" @default.
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- W2023883460 doi "https://doi.org/10.1021/jp002926z" @default.
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