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- W2023885770 abstract "High-pressure reactions of tributyltin hydride with several chloroketones (3- chloro-2-butanone, 4-chloro-2-butanone, 5-chloro-2-pentanone, 6-chloro-2-hexanone and 7-chloro-2-heptanone) led to the formation of chloroalkoxytins or cyclic ethers. An ionic mechanism, starting with nucleophilic attack at the carbonyl group, is proposed to explain the formation of the reaction products. Les chloro-3 butanone-2, chloro-4 butanone-2, chloro-5 pentanone-2, chloro-6 hexanone-2, chloro-7 heptanone-2 ont été soumis à l'action de l'hydrure de tributylétain sous haute pression (14 kbars). L'étude des différents produits de réaction, principalement des hétérocycles oxygénés et des chloroalcoxyétains, montre qu'ils résultent vraisemblablement de l'attaque nucléophile de l'hydrure de tributylétain sur le carbonyle." @default.
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- W2023885770 date "1985-05-01" @default.
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- W2023885770 title "Chimie organometallique sous haute pression: Reaction des chlorocetones avec l'hydrure de tributyletain" @default.
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- W2023885770 doi "https://doi.org/10.1016/0022-328x(85)80067-x" @default.
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