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• W2023886919 abstract "The electron paramagnetic resonance of the Tl2+ centre in the two chemically distinct ammonium sites in (NH4)2SO4 was investigated in the temperature range 85-227 K. The mirror symmetry of the sites in the paraelectric phase is preserved by the impurity. At Tc the spin-Hamiltonian tensors undergo discontinuous rotations which keep on increasing with decreasing temperature in the ferroelectric phase. The different rotations, in amplitude and direction, for the spin-Hamiltonian tensors associated with the two inequivalent ammonium sites are consistent with the ferrielectric model of (NH4)2SO4. The coexistence of the two phases is observed at about 4 K below Tc." @default.
• W2023886919 created "2016-06-24" @default.
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• W2023886919 date "1992-07-27" @default.
• W2023886919 modified "2023-09-26" @default.
• W2023886919 title "Phase transition structural changes of (NH4)2SO4investigated by electron paramagnetic resonance of the Tl2+ion" @default.
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• W2023886919 doi "https://doi.org/10.1088/0953-8984/4/30/013" @default.
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