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• W2023887340 startingPage "911" @default.
• W2023887340 abstract "The interaction in aqueous media of 4,6-dimethyl-1,2,3-triazolo[4,5-d]pyrimidin-5,7-dione (1,3-dimethyl-8-azaxanthine, Hdmax) with salts of divalent Mn, Co, Ni, Cu, Zn and Cd in the presence of an excess of pyridine (py) leads to the formation of crystalline solids, the structures of which have been solved by single crystal X-ray diffraction. The solids containing Mn, Co, Zn and Cd are isostructural, presenting a formulation trans-[M(H2O)4(py)2](dmax)2, with the heterocycle in the anionic form and not directly linked to the metal atom. The H-bond network of these complexes include a tape superstructure topologically identical to that present in the previously reported hexa-aqua salts of the dmax− anion, which may be regarded as a case of molecular recognition between dmax− and the square planar [M(H2O)4] subunit. On the other hand, for Ni and Cu the triazolopyrimidine ligand is directly coordinated to the metal through the external imidazole nitrogen atom (N2) generating the compounds [M(dmax)2(H2O)2(py)2] · 2H2O, which display a less tight H-bonding network." @default.
• W2023887340 created "2016-06-24" @default.
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• W2023887340 date "2009-04-01" @default.
• W2023887340 modified "2023-10-13" @default.
• W2023887340 title "First and second coordination spheres in divalent metal compounds containing pyridine and 4,6-dimethyl-1,2,3-triazolo[4,5-d]pyrimidin-5,7-dione" @default.
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• W2023887340 doi "https://doi.org/10.1016/j.poly.2009.01.037" @default.
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